Emulsion separation, a focal and difficult side of oil-water separation processes, had lengthy been a supply of frustration for researchers because of the phenomenon of flux decline brought on by focus polarization and adhesion of oil droplets through the separation course of. Makes an attempt had been made to deal with membrane fouling points by means of catalytic degradation and bubble flotation strategies, but the flux decline phenomenon persevered. On this work, through the fabrication course of, intermolecular forces had been utilized to polarize polyvinylidene difluoride molecular chains to extend β-phase and endow with piezoelectric properties. The ready piezoelectric membrane, beneath the variable stress surroundings created by a peristaltic pump, may keep a steady flux all through the separation course of with out decline, versus fixed stress filtration. It was discovered that the primary mechanism of motion was dielectrophoretic drive, and the feasibility was theoretically analyzed, holding promise for the extension to the separation of a larger number of oil-in-water emulsions. Moreover, the piezoelectric catalytic impact may generate reactive oxygen species, which may additional degrade natural pollution to alleviate membrane floor contamination and blockage, additional sustaining flux. This work supplied new insights for the event of emulsion separation purposes.